The suspect from the Aug. 15 CVS robbery in Chicopee was arrested at Penn Station in New York City.
Chicopee police said Dario Albizu-Ventura was arrested by Amtrack police at the end of August.
Albizu-Ventura waived extradition at the Manhattan Central Court Tuesday. He is now back in Chicopee to be arraigned on armed robbery and larceny charges.
Police said Albizu-Ventura is also being investigated for robberies in Holyoke, Westfield and Longmeadow.
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